When 10:30 AM - 11:30 AM Mar 23, 2018
Where 1670 Beyster
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Entropy-Stabilized Oxides

Jon-Paul Maria
Penn State University

The hunt for new phases of matter is among the most exciting activities in materials research. The excitement originates from the possibility of active property engineering and advanced technology opportunities that serve societal needs. As a community, we have been looking for a long time, and given the finite number of practical elements and their stable combinations, it is not clear how many are left to find especially if we limit ourselves to conventional tactics. In response, researchers are exploring new approaches that include artificial layering, high throughput computation, severely confined dimensions, and strain-stabilization.

This presentation will introduce the concept of entropy engineering, which is a parallel path to new materials discovery. In this approach, many cations are distributed at random among a single sublattice creating a high degree of configurational disorder. At finite temperatures, these systems can minimize free energy by remaining single phase. While such processes are known in nature, i.e., the energetics that regulate site occupancy in spinels, they were adopted recently by the metallurgy community to create a new class of engineering alloys with compelling mechanical properties.

The Maria group extended this concept to complex oxides to demonstrate without ambiguity that new phases of matter can be stabilized by configurational disorder. These crystalline materials are referred to as Entropy-Stabilized Oxides (ESOs) and feature local coordination values that are uncommon in natural and synthetic materials.

Using a series of solid-state chemistry experiments, a simple thermodynamic model, and a five-component oxide formulation, we demonstrate beyond reasonable doubt that entropy can predominate the thermodynamic landscape, and drive a reversible solid-state transformation between multiphase and single phase states, where in the latter, cation distributions are random and homogeneous. The findings validate the hypothesis that deliberate configurational disorder provides an orthogonal strategy to imagine new phases of crystalline matter and exploit new opportunities for property engineering.

Finally, we will demonstrate how the palette of entropy-stabilized oxides can be expanded when the formulations are prepared using physical vapor deposition, i.e., the range of compositions that become entropy stabilized increase substantially upon thin film preparation as compared to bulk solid-state synthesis. At this stage we speculate that kinetic energy of the incoming species provides an effective temperature that increases the entropic contribution to free energy. This methods leads to even more unusual cation accommodation and immediate possibilities for lattice constant engineering beyond the limits of conventional solid solution. 



Jon-Paul Maria is a Professor of Materials Science and Engineering at The Pennsylvania State University and a Professor Emeritus at North Carolina State University where he spent 15 years serving on Materials Science and Engineering faculty. Prior to joining NCSU, Jon-Paul received his BS., MS, and Ph.D. degrees from Penn State in Ceramic Science. Jon-Paul’s research group pursues new materials discovery, property engineering, advances in synthesis science, and new integration strategies to merge diverse materials. Laboratory activities of interest include physical vapor deposition, ceramic synthesis by powder processing, structural characterization by diffraction, and microstructure measurement using scanning probe and scanning electron microscopy. The Maria Group members currently pursue research in the areas of ferroelectric thin films, high permittivity materials, novel semiconductor contacts, oxide epitaxy, infra-red plasmonic materials and entropy engineered/stabilized crystals. With assistance from many collaborators, The Maria group published over 240 publications dealing with structure-property-processing relationships in electronic materials. In 2016 Jon-Paul co-founded Third Floor Materials, a startup company that endeavors to develop novel IR sensor materials and technologies.

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