When 10:15 AM - 11:30 AM Feb 03, 2023
Where 1013 H.H. Dow
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"Mixed-Dimensional Heterostructures for Electronic and Energy Technologies"

Mark Hersam
Northwestern University

Layered two-dimensional (2D) materials interact primarily via van der Waals bonding, which has created new opportunities for heterostructures that are not constrained by epitaxial growth [1,2]. However, it is important to acknowledge that van der Waals interactions are not limited to interplanar interactions in 2D materials. In principle, any passivated, dangling bond-free surface interacts with another via non-covalent forces. Consequently, layered 2D materials can be integrated with a diverse range of other materials, including those of different dimensionality, to form mixed-dimensional van der Waals heterostructures [3]. Furthermore, chemical functionalization provides additional opportunities for tailoring the properties of 2D materials [4] and the degree of coupling across heterointerfaces [5]. In order to efficiently explore the vast phase space for mixed-dimensional heterostructures, our laboratory employs solution-based additive assembly. In particular, constituent nanomaterials (e.g., carbon nanotubes, graphene, transition metal dichalcogenides, black phosphorus, boron nitride, and indium selenide) are isolated in solution, and then deposited into thin films with scalable additive manufacturing methods [6-8]. By achieving high levels of nanomaterial monodispersity and printing fidelity, a variety of electronic and energy applications can be enhanced including photodetectors, optical emitters, supercapacitors, and batteries [9-14]. Furthermore, by integrating multiple nanomaterials into heterostructures, unprecedented device function can be realized including anti-ambipolar transistors, gate-tunable Gaussian heterojunction transistors, and neuromorphic memtransistors [15-18]. In addition to technological implications for electronic and energy technologies, this talk will explore several fundamental issues including band alignment, doping, trap states, and charge/energy transfer across van der Waals heterointerfaces.



[1] D. Lam, et al.ACS Nano16, 7144 (2022).

[2] H. Bergeron, et al.Chemical Reviews121, 2713 (2021).

[3] D. Jariwala, et al.Nature Materials16, 170 (2017).

[4] S. H. Amsterdam, et al.Journal of Physical Chemistry Letters12, 4543 (2021).

[5] S. Padgaonkar, et al.Accounts of Chemical Research53, 763 (2020).

[6] C. M. Thomas, et al.ACS Energy Letters7, 1558 (2022).

[7] W. J. Hyun, et al.Nano Letters22, 5372 (2022).

[8] D. Lam, et al.ACS Nano16, 11315 (2022).

[9] M. E. Beck and M. C. Hersam, ACS Nano14, 6498 (2020).

[10] K.-Y. Park, et al.Advanced Energy Materials10, 2001216 (2020).

[11] W. J. Hyun, et al.Advanced Materials33, 2007864 (2021).

[12] K.-Y. Park, et al.Advanced Materials34, 2106402 (2022).

[13] N. S. Luu, et al.Accounts of Materials Research3, 511 (2022).

[14] L. Kuo, et al.Advanced Materials34, 2203772 (2022).

[15] M. E. Beck, et al.Nature Communications11, 1565 (2020).

[16] V. K. Sangwan and M. C. Hersam, Nature Nanotechnology15, 517 (2020).

[17] J. Yuan, et al.Nano Letters21, 6432 (2021).

[18] X. Yan, et al.Advanced Materials34, 2108025 (2022).